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Kapeghian, Jesse; Amoroso, Danila; Occhialini, Connor_A; Martins, Luiz_G_P; Song, Qian; Smith, Jesse_S; Sanchez, Joshua_J; Kong, Jing; Comin, Riccardo; Barone, Paolo; et al (, Physical Review B)
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Huston, Larissa_Q; Couper, Samantha_C; Jacobsen, Matthew; Moss, Eric_K; Miyagi, Lowell; Smith, Jesse_S; Velisavljevic, Nenad; Sturtevant, Blake_T (, Journal of Applied Physics)Cerium oxide (ceria, CeO2) is frequently used as a standard in applications such as synchrotron and x-ray free electron lasers for calibrating x-ray wavelengths and offers the potential for understanding the high pressure properties and deformation mechanisms in a wide range of similar face centered cubic (fcc) materials. In this study, the pressure dependence of the strength of ceria was investigated up to 38 GPa using angle dispersive x-ray diffraction in a radial geometry in a diamond anvil cell. In this experiment, the difference in the stress along the axis of compression and perpendicular to the direction of compression can be determined, giving a quantity known as the differential stress. It was found that the differential stress (t), a measure of the lower bound for yield strength, initially increases rapidly from 0.35 ± 0.06 GPa to 2.2 ± 0.4 GPa at pressures of 1.8 and 3.8 GPa, respectively. Above 4 GPa, t increases more slowly to 13.8 ± 2.6 GPa at a pressure of 38 GPa. The changes in the preferred orientation (texture) of CeO2 with pressure were also measured, allowing for the determination of active deformation mechanisms using an elasto-viscoplastic self-consistent model (EVPSC). It was found that as pressure increased, the [001] direction had a slight preferred orientation along the axis of compression. Our EVPSC model of experimental fiber (cylindrically symmetric) textures and lattice strains were most consistent with dominant slip activity along {111}⟨11¯0⟩.more » « less
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